Neutralization of Static Charges by Air Ions: Part II, Experimental
Results
This
second installment on charge neutralization demonstrates that
a CPM can be used to determine fundamental atmospheric electric
quantities.
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Niels Jonassen
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The
most commonly used instrument for evaluating the ionization
state of an atmosphere is the charged-plate monitor (CPM)
shown in Figure 1. In the figure, a metal plate with the
area A is placed a distance d from a ground plate in which
is inserted a fieldmeter probe. The charged plate can be
charged to a selected voltage (usually 1 or 5 kV), and the
voltage can be measured on the fieldmeter.
When
an atmosphere or ionization system is to be evaluated, the
charged plate is exposed to the atmosphere, charged to a
selected voltage, and the time, t10,
for the voltage to drop to one-tenth of the starting voltage
is measured. This time depends on the geometry of the CPM
and the negative resistivity of the air if a positive voltage
is chosen. Consequently, it is not possible to use a CPM
measurement to predict directly how fast an arbitrary item
will be neutralized, even when both the CPM and the item
are exposed to the same atmosphere. However, in many cases,
the neutralization time for an item can be deduced indirectly
from CPM measurements.
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Figure
1. Charged-plate monitor.
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Theory
of a CPM
In
Part I of this article, it was shown that the charge on
a positively charged body suspended freely in air will be
neutralized exponentially with a time constant of
,
(1)
where
r is the resistivity of the air due to
negative ions.1
The
time constant in an exponential decay is the time it takes
the decaying quantity to drop to 1/e of the initial value,
with e being the base of the natural logarithm (≈ 2.72).
Consequently, for any system with the time constant t, there
is the relationship
.
(2)
The
time constant to
(known as the fundamental time constant) given by
Equation 1 is the lowest time constant for any system in
an atmosphere characterized by the parameters eo
and r.
Figure
2 shows a system consisting of a positively charged metal plate
with the area A, separated from ground by a dielectric
with the thickness d and the relative permittivity er.
In Part I, it was suggested that the plate A, when exposed to
an atmosphere with the fundamental time constant t+o,
would have a time constant t+
given by
, (3)
where
. (4)
The
variable r is the (equivalent) radius of the metal
plate
,
where
O is the circumference of plate A. The variable er
is the relative permittivity of the dielectric. The capacitance
Ca of the metal plate relative
to the air was approximated by
. (5)
Introducing
Equations 4 and 5 into Equation 3 gives
. (6)
When
applying Equation 3 on a CPM, as shown in Figure 1, Equation
6 reduces to
, (7)
because
er = 1
for air.
It
should be mentioned that, in some CPMs, the plate voltage
is monitored by a noncontacting voltmeter, which may add
a stray capacitance Cs from
the support. In such cases, the factor

should
be replaced by
.
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Figure
2. Charged plate near ground.
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Experimental
Results
To
verify experimentally the relationship expressed in Equation
7, it is necessary to be able to establish an atmosphere
with a known value for to.
Although the fundamental time constant, to,
cannot be measured directly, Equation 1 may be reformulated,
writing r as
, (8)
where
e is the electronic (and small-ion) charge, k
is the mobility of negative ions, and n
is the relevant negative-ion concentration.
Combining
Equations 1, 4, and 5 gives the following results:
(9)
and
(10)
The
constants in Equations 4, 5, 9, and 10 had the following
values: r = 9 ·
102
m, d = 1.5 ·
102
m, eo =
8.85 ·
1012
F ·
m1,
e = 1.6 ·
1019
C, k ≈ 1.8 ·
104
m2 ·
V1
·
s1,
and k+ ≈ 1.4 ·
104
m2 ·
V1
·
s1.
Substituting these values into the relevant equations results
in the following capacitance and decay-time values to be
recorded on the CPM: Cd = 15
pF, Ca = 5 pF,
,
(11)
and
.
(12)
The
setup shown in Figure 3 was used for the experiments. An
ionizer was placed at a well-defined distance from an ion-density
meter. Because an ion blower was used as the ionizer, the
air intake of the ion-density meter was placed perpendicular
to the airflow so that the airflow would not be disturbed
through the meter. The CPM was placed on top of the ion-density
meter. It is important that the field from the charged plate
is insignificant at the air intake, and the placement on
top of the ion-density meter turned out to be the best because
the CPM also needed to be exposed to the ionized airflow.
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Figure
3. Experimental setup.
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A
series of experiments were performed in which the positive-
and negative-ion density and the corresponding decay times
(t10 values) were measured.
The ion densities were varied by varying the distance a
between the ionizer and the ion-density meter. For each
distance, the average ion density and the decay times for
positive and negative voltages were measured. The results
are shown in Table I. Each of the decay times is the average
of five measurements.
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Distance
a (m)
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n+
(1011 ions/m3)
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n
(1011 ions/m3)
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t+10
(seconds)
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t10
(seconds)
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Ion
blower
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1
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3.23.6
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2.52.9
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11.8
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12.3
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1.5
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2.22.6
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1.82.2
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16.9
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17.7
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2
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1.01.4
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0.81.2
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32.0
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34.1
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2.5
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0.40.6
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0.20.4
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105
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83.7
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Ion
bar
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1
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0.200.24
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0.160.20
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180
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190
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Table
I. Ion concentrations and CPM decay times.
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To
compare the experimental results with the predictions of
Equations 11 and 12, the products

and

were
calculated with the following
results:
(13)
and
.
(14)
It
appears that the coefficients in the experimentally determined
Equations 13 and 14 are 1415% greater than the theoretical
values of the corresponding Equations 12 and 11, respectively.
This discrepancy must be caused by the approximation used
in evaluating the air capacitance Ca
(Equation 5), which overestimated the capacitance by about
19%. Therefore, Equation 5 should read
,
(5a)
resulting
in Ca = 4.2 pF for the CPM
investigated. Correspondingly, Equations 6, 7, 9, and 10
become
,
(6a)
,
(7a)
,
(9a)
and
.
(10a)
Discussion
of the Results
The
equations developed in this article indicate that, by the
use of a CPM with given geometric and dielectric characteristics,
it is possible to predict the ion concentrations and resistivities
of a given (ionized) atmosphere. However, a more-important
implication is that it is, in many cases, also possible
to estimate how fast an ordinary charged item (i.e., not
just a CPM) will be neutralized in a given atmosphere.
For
example, if Equation 7a is applied on the CPM used in this
investigation (i.e., r = 9 ·102
m and d = 1.5 ·102
m), the result would be
.
(7b)
Equation
7b indicates that, for a given atmosphere, the CPM will
measure a time constant that is 4.57 times greater than
the fundamental time constant for the atmosphere in question.
Now
assume there is an item like that shown in Figure 2, with
a charged metal plate A, an effective radius ri
= 0.1 m, a thickness di = 10-2
m, and a relative permittivity er,i =
4.0. According to Equation 6a, the time constant should
be
.
(6b)
Combining
Equation 6b with 7b results in
.
(15)
It
is therefore possible to use a CPM measurement to predict
how fast a charged metal plate, separated from ground by
a dielectric, will be neutralized.
Labeling
the parameters of the CPM with c and of the item with i,
the general equation relating a predicted neutralization
time with the corresponding time measured by a CPM will
be
.
(16)
Equation
16 is valid for positive as well as negative voltages, corresponding
to ions of opposite polarities, and for time constants as
well as for t10 times.
Insulators
As
was explained in Part I, the neutralization of a charge
located on the surface of a dielectric follows the same
rules as that of a charge located on the surface of a conductive
plate.1 The equations in this article are therefore
valid when ri is the radius
of the charged area, er,i
is the relative permittivity, and di
is the thickness of the dielectric.
Conclusion
It
has been demonstrated that it is possible to use a CPM with
given dimensions to determine fundamental atmospheric electric
quantities such as ion density and resistivity. Furthermore,
it has been shown that the neutralization time for commonly
shaped charged conductors, as well as for insulators, can
be deduced from measurements of the neutralization time
with a CPM.
Acknowledgment
The
cooperation of Ion Systems (Culemborg, The Netherlands)
and Simco (Lochem, The Netherlands) for allowing the use
of their ion blower and ion bar, respectively, is greatly
appreciated.
Reference
1.
Niels Jonassen, "Neutralization of Static Charges by Air Ions:
Part 1, Theory" in Mr. Static, Compliance Engineering 19,
no. 4 (2002): 2831.
Niels
Jonassen, MSc, DSc, worked for 40 years at the Technical University
of Denmark, where he conducted classes in electromagnetism, static
and atmospheric electricity, airborne radioactivity, and indoor
climate. After retiring, he divided his time among the
laboratory, his home, and Thailand, writing on static
electricity topics and pursuing cooking classes. He passed away in 2006.
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